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<article article-type="research-article">
<front>
<journal-meta>
<journal-id journal-id-type="archive">gsminmag</journal-id>
<journal-title>Mineralogical Magazine</journal-title>
<abbrev-journal-title abbrev-type="full">Mineralogical Magazine</abbrev-journal-title>
<issn pub-type="ppub">0026-461X</issn>
<publisher>
<publisher-name>Mineralogical Society</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.1180/minmag.1994.058.390.14</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Extraterrestrial Material</subject>
</subj-group>
</article-categories>
<title-group>
<article-title>M&#x00F6;ssbauer Study of Redox Processes in the Evolution of Chondrites</article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Malysheva</surname>
<given-names>T. V.</given-names>
</name>
<aff>V. I. Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow, Russia</aff></contrib></contrib-group>
<pub-date pub-type="ppub">
<month>3</month>
<year>1994</year>
</pub-date>
<volume>58</volume>
<issue>390</issue>
<fpage>151</fpage>
<lpage>158</lpage>
<history>
<date date-type="received">
<day>6</day>
<month>2</month>
<year>1992</year>
</date>
<date date-type="rev-recd">
<day>23</day>
<month>7</month>
<year>1993</year>
</date></history>
<copyright-statement>Copyright &#x00A9; 1994, The Mineralogical Society</copyright-statement>
<copyright-year>1994</copyright-year>
<abstract>
<title>Abstract</title>
<p>The evolution of Fe-containing phases of carbonaceous chondrites heated under various oxidation-reduction conditions was investigated by means of M&#x00F6;ssbauer spectroscopy. Heating of the lower petrological types of chondrites (CM2) released gases which initially produced oxidizing conditions (&#x223C;450&#x00B0;C) and then reducing conditions (&#x003E; 700&#x00B0;C Phase transformation occurred rapidly (during 1&#x2013;5 minutes) at all temperatures. During heating the Fe-bearing phyllosilicate phases in CM2-chondrite converted to Fe-bearing olivine, metallic iron and troilite (pentlandite). These phases resemble those of CO3, CV3 and EH-chondrites. Iron distribution resembling that of ordinary chondrites (some additional Fe<sup>2+</sup> in pyroxene) was obtained only by heating a mixture of oxidized matter (CM2) with reduced matter (EH).</p>
<p>A phase transition discovered at 1050&#x00B0;C is probably the temperature boundary between conditions of formation of the two main components of ordinary chondrites: matrix and chondrules. Chondrules of ordinary chondrites may be formed at temperatures &#x003E; 1050&#x00B0;C while the matrix forms at temperatures &#x003C; 1050&#x00B0;C For the carbonaceous chondrite Kainzas (CO3) these temperatures are approximately 1000&#x00B0;C and &#x003C; 900&#x00B0;C The experimental conditions determined for the evolution of chondrites do not contradict the theoretical two-component model of Wood-Anders-Ringwood and may further its development.</p></abstract>
<kwd-group>
<title>Keywords</title>
<kwd>chondrites</kwd>
<kwd>M&#x00F6;ssbauer study</kwd>
<kwd>iron-bearing minerals</kwd>
<kwd>redox processes</kwd>
</kwd-group>
</article-meta>
</front>
</article>
