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<article article-type="rapid-communication">
<front>
<journal-meta>
<journal-id journal-id-type="archive">gsminmag</journal-id>
<journal-title>Mineralogical Magazine</journal-title>
<abbrev-journal-title abbrev-type="full">Mineralogical Magazine</abbrev-journal-title>
<issn pub-type="ppub">0026-461X</issn>
<publisher>
<publisher-name>Mineralogical Society</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.1180/minmag.1991.055.378.11</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Short Communications</subject>
</subj-group>
</article-categories>
<title-group>
<article-title>Kegelite: Infrared Spectroscopy and a Structural Hypothesis</article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Braithwaite</surname>
<given-names>R. S. W.</given-names>
</name>
<aff>Chemistry Department, University of Manchester Institute of Science and Technology, Manchester M60 1QD, England</aff></contrib></contrib-group>
<pub-date pub-type="ppub">
<month>3</month>
<year>1991</year>
</pub-date>
<volume>55</volume>
<issue>378</issue>
<fpage>127</fpage>
<lpage>134</lpage>
<history>
<date date-type="received">
<day>11</day>
<month>3</month>
<year>1990</year>
</date></history>
<copyright-statement>Copyright &#x00A9; 1991, The Mineralogical Society</copyright-statement>
<copyright-year>1991</copyright-year>
<abstract>
<title>Abstract</title>
<p>The infrared spectrum of kegelite has been measured and is discussed. The infrared spectra of 1 : 1 molar mixtures of leadhillite with pyrophyllite or with muscovite resemble the spectrum of kegelite, the chemical formula of which is a 1 : 1 stoichiometric sum of those of pyrophyllite and of the leadhillite polymorphs. Kegelite is not a physical mixture of these species, but its structure may be an interlayering of phyllosilicate and leadhillite-like structures within the unit cell. The unit cell parameters of pyrophyllite-1<italic>Tc</italic> and the leadhillite polymorphs are compatible with each other and can be combined to give a cell with parameters close to those of the kegelite cell. A structural model for kegelite on these bases is suggested, which is also consistent with its thermal analysis. The formula of kegelite can be written as Pb<sub>8</sub>(SO<sub>4</sub>)<sub>2</sub>(CO<sub>3</sub>)<sub>4</sub>(OH)<sub>4</sub>(AlOH)<sub>4</sub>(Si<sub>4</sub>O<sub>10</sub>)<sub>2</sub>.</p></abstract>
<kwd-group>
<title>Keywords</title>
<kwd>kegelite</kwd>
<kwd>infrared spectrum</kwd>
<kwd>pyrophyllite</kwd>
<kwd>leadhillite</kwd>
</kwd-group>
</article-meta>
</front>
</article>
