Manganian andalusite occurs abundantly as porphyroblasts in manganiferous metasediments subjected to contact metamorphism under hornblende hornfels facies at the contact of a picrodolerite dyke near Manbazar, Purulia District, India. The Mn₂O₃ content of andalusite varies from 13.2% to 19.17%, corresponding to 14.8 and 21.14 mole per cent of ‘Mn₂SiO₅’ respectively. Based on the analysis showing maximum amount of Mn₂O₃ in andalusite, the mineral formula may be represented as follows: (Mn0.433+Al0.50Fe0.093+)1.02[6]Al1.00[5][O1.00∕Si0.98O4.00]

Other minerals in the assemblage are muscovite, manganophyllite, spessartine, piemontite, quartz, braunite, hematite and rutile. The manganian andalusite is completely fresh and appears to have formed at the expense of spessartine, piemontite and braunite during contact metamorphism. The manganian andalusite probably formed at about 600°C at around 3 kbar pressure. This is another rare example of andalusite with very high Mn₂O₃ (and Fe₂O₃) as well as that of an occurrence of abundant manganian andalusite.