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<article article-type="research-article">
<front>
<journal-meta>
<journal-id journal-id-type="archive">gsminmag</journal-id>
<journal-title>Mineralogical Magazine</journal-title>
<abbrev-journal-title abbrev-type="full">Mineralogical Magazine</abbrev-journal-title>
<issn pub-type="ppub">0026-461X</issn>
<publisher>
<publisher-name>Mineralogical Society</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.1180/minmag.1986.050.355.21</article-id>
<article-categories>
<subj-group subj-group-type="heading">
<subject>Crystal Structures</subject>
</subj-group>
</article-categories>
<title-group>
<article-title>The Crystal Structure and Chemical Composition of Cumeng&#x00E9;ite</article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Hawthorne</surname>
<given-names>F. C.</given-names>
</name></contrib>
<contrib contrib-type="author">
<name>
<surname>Groat</surname>
<given-names>L. A.</given-names>
</name></contrib>
<aff>Department of Earth Sciences, University of Manitoba, Winnipeg, Manitoba, Canada, R3T 2N2</aff></contrib-group>
<pub-date pub-type="ppub">
<month>3</month>
<year>1986</year>
</pub-date>
<volume>50</volume>
<issue>355</issue>
<fpage>157</fpage>
<lpage>162</lpage>
<history>
<date date-type="received">
<day>25</day>
<month>4</month>
<year>1985</year>
</date>
<date date-type="rev-recd">
<day>19</day>
<month>6</month>
<year>1985</year>
</date></history>
<copyright-statement>Copyright &#x00A9; 1986, The Mineralogical Society</copyright-statement>
<copyright-year>1986</copyright-year>
<abstract>
<title>Abstract</title>
<p>The crystal structure of cumeng&#x00E9;ite, Pb<sub>21</sub>Cu<sub>20</sub>Cl<sub>42</sub>(OH)<sub>40</sub>, tetragonal, <italic>a</italic>= 15.065(2), <italic>c</italic>= 24.436(5) &#x00C5;, V = 5546(2) &#x00C5;<sup>3</sup>, space group I4/<italic>mmm</italic>, Z = 2, has been solved by direct methods and refined by least-squares to an <italic>R</italic> index of 7.1 % for 1158 observed (<italic>I</italic> &#x003E; 2.5<italic>&#x03C3; I</italic>) reflections. The cumeng&#x00E9;ite structure shows a very diverse range of cation coordinations. There are five distinct Pb sites with the following coordination polyhedra: octahedron, square antiprism, augmented trigonal prism, a very distorted biaugmented trigonal prism and a fairly regular biaugmented trigonal prism, the latter being only half-occupied; there are two distinct Cu sites with octahedral and square pyramidal coordination respectively. The coordination polyhedra share elements to form prominent columns or rods of polyhedra parallel to the <italic>c</italic>-axis and centred on the 4-fold axes of the unit cell. These rods form a body-centred array, and link by sharing elements of their coordination polyhedra.</p></abstract>
<kwd-group>
<title>Keywords</title>
<kwd>cumeng&#x00E9;ite</kwd>
<kwd>crystal structure</kwd>
</kwd-group>
</article-meta>
</front>
</article>
