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<front>
<journal-meta>
<journal-id journal-id-type="archive">gsminmag</journal-id>
<journal-title>Mineralogical Magazine</journal-title>
<abbrev-journal-title abbrev-type="full">Mineralogical Magazine</abbrev-journal-title>
<issn pub-type="ppub">0026-461X</issn>
<publisher>
<publisher-name>Mineralogical Society</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.1180/minmag.1977.041.320.14</article-id>
<title-group>
<article-title>Janggunite, a New Manganese Hydroxide Mineral from the Janggun Mine, Bonghwa, Korea</article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Kim</surname>
<given-names>Soo Jin</given-names>
</name><xref ref-type="author-notes" rid="FN1">1</xref>
<aff>Mineralogisches Institut der Universit&#x00E4;t Heidelberg, 69 Heidelberg, West Germany</aff></contrib></contrib-group>
<author-notes>
<fn fn-type="present-address" id="FN1"><label>1</label><p>Present address: Department of Geology, College of Natural Sciences, Seoul National University, Seoul 151, Korea.</p></fn></author-notes>
<pub-date pub-type="ppub">
<month>12</month>
<year>1977</year>
</pub-date>
<volume>41</volume>
<issue>320</issue>
<fpage>519</fpage>
<lpage>523</lpage>
<history>
<date date-type="received">
<day>8</day>
<month>3</month>
<year>1977</year>
</date></history>
<copyright-statement>Copyright &#x00A9; 1977, The Mineralogical Society</copyright-statement>
<copyright-year>1977</copyright-year>
<abstract>
<title>Summary</title>
<p>Janggunite occurs as radiating groups of flakes, flower-like aggregates, colloform bands, dendritic or arborescenl masses in the cementation zone of the supergene manganese oxide deposits. The flakes average 0&#x00B7;05 mm. Colour black, lustre dull, streak brownish black to dark brown. Cleavage one direction perfect. H = 23, very fragile. <italic>D</italic><sub>meas</sub> = 3&#x00B7;59, <italic>D</italic><sub>calc</sub> = 3&#x00B7;58. Under reflected light anisotropic and bireflectant. No internal reflections. Etching reactions: positive - HC1, HNO<sub>3</sub>, SnCl<sub>2</sub>, H<sub>2</sub>O<sub>2</sub>, H<sub>2</sub>SO<sub>4</sub> + H<sub>2</sub>O<sub>2</sub>. Chemical formula, <inline-formula><mml:math><mml:mrow><mml:msubsup> <mml:mrow><mml:mi>Mn</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn><mml:mo>&#x00B7;</mml:mo><mml:mn>85</mml:mn></mml:mrow><mml:mrow><mml:mn>4</mml:mn><mml:mo>&#x002B;</mml:mo></mml:mrow></mml:msubsup><mml:mrow><mml:mo>(</mml:mo><mml:msubsup> <mml:mrow><mml:mi>Mn</mml:mi></mml:mrow><mml:mrow><mml:mn>0</mml:mn><mml:mo>&#x00B7;</mml:mo><mml:mn>90</mml:mn></mml:mrow><mml:mrow><mml:mn>2</mml:mn><mml:mo>&#x002B;</mml:mo></mml:mrow></mml:msubsup><mml:msubsup> <mml:mrow><mml:mi>Fe</mml:mi></mml:mrow><mml:mrow><mml:mn>0</mml:mn><mml:mo>&#x00B7;</mml:mo><mml:mn>30</mml:mn></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>&#x002B;</mml:mo></mml:mrow></mml:msubsup><mml:mo>)</mml:mo></mml:mrow><mml:msub><mml:mo>O</mml:mo><mml:mrow><mml:mn>8</mml:mn><mml:mo>&#x00B7;</mml:mo><mml:mn>09</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mi>OH</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:mn>5</mml:mn><mml:mo>&#x00B7;</mml:mo><mml:mn>91</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> on the basis of O = 14, or ideally <inline-formula><mml:math><mml:mrow><mml:msubsup><mml:mrow><mml:mi>Mn</mml:mi></mml:mrow><mml:mrow><mml:mn>5</mml:mn><mml:mo>&#x2212;</mml:mo><mml:mi>x</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn><mml:mo>&#x002B;</mml:mo></mml:mrow></mml:msubsup><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:msup><mml:mi>Mn</mml:mi><mml:mn>2+</mml:mn><mml:mo>&#x002B;</mml:mo></mml:msup><mml:msup><mml:mi>Fe</mml:mi><mml:mn>3+</mml:mn><mml:mo>&#x002B;</mml:mo></mml:msup><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:mn>1</mml:mn><mml:mo>&#x002B;</mml:mo><mml:mi>x</mml:mi></mml:mrow></mml:msub><mml:msub><mml:mo>O</mml:mo><mml:mn>8</mml:mn></mml:msub><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mi>OH</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mn>6</mml:mn></mml:msub><mml:mo>(</mml:mo><mml:mi>x</mml:mi><mml:mspace width="veryth:nmathspace"/><mml:mo>&#x003D;</mml:mo><mml:mspace width="veryth:nmathspace"/><mml:mn>0</mml:mn><mml:mo>&#x00B7;</mml:mo><mml:mn>2</mml:mn><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. The mineral has an orthorhombic unit cell with <italic>a</italic> 9&#x00B7;324, <italic>b</italic> 14&#x00B7;05, <italic>c</italic> 7&#x00B7;956 &#x00C5;, Z = 4, <italic>a:b:c</italic> = 0&#x00B7;663:1:0&#x00B7;566. Important diffraction lines are 9&#x00B7;34(s), 7&#x00B7;09(s), 4&#x00B7;62(m), 4&#x00B7;17(m), 3&#x00B7;547(s), 3&#x00B7;101(s), 2&#x00B7;597(w), 2&#x00B7;469(m), 1&#x00B7;863(w), 1&#x00B7;664(w), 1&#x00B7;525(m), 1&#x00B7;405(m), D.T.A. curve shows the endothermic peaks at 250&#x2013;370&#x00B0;C and 955&#x00B0;C Infra-red absorption spectral curve shows vibrations at 515 cm<sup>&#x2212;1</sup>, 545 cm<sup>&#x2212;1</sup>, 1025 cm<sup>&#x2212;1</sup>, and 3225 cm<sup>&#x2212;1</sup>. The mineral and name have been approved before publication by the Commission on New Minerals and Mineral Names, I.M.A.</p></abstract>
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