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<front>
<journal-meta>
<journal-id journal-id-type="archive">gsminmag</journal-id>
<journal-title>Mineralogical Magazine</journal-title>
<abbrev-journal-title abbrev-type="full">Mineralogical Magazine</abbrev-journal-title>
<issn pub-type="ppub">0026-461X</issn>
<publisher>
<publisher-name>Mineralogical Society</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.1180/minmag.1965.035.270.03</article-id>
<title-group>
<article-title>Pandaite from the Mrima Hill Niobium Deposit (Kenya)</article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Harris</surname>
<given-names>P. M.</given-names>
</name><degrees>B.A.</degrees>
<aff>Warren Spring Laboratory, D.S.I.R., Stevenage, Herts.</aff></contrib></contrib-group>
<pub-date pub-type="ppub">
<month>6</month>
<year>1965</year>
</pub-date>
<volume>35</volume>
<issue>270</issue>
<fpage>277</fpage>
<lpage>290</lpage>
<history>
<date date-type="received">
<day>2</day>
<month>10</month>
<year>1964</year>
</date></history>
<copyright-statement>Copyright &#x00A9; 1965, The Mineralogical Society</copyright-statement>
<copyright-year>1965</copyright-year>
<abstract>
<title>Summary</title>
<p>A hydrated barium pyrochlore (pandaite) has been found at Mrima Hill (Kenya) in a residuum consisting mainly of goethite/limonite and gorceixite. The pandaite occurs as pale yellow or white octahedral crystals, which have a micro-crystalline interior. It is isotropic, the refractive index varies from 2&#x00B7;07 to 2&#x00B7;11. The calculated specific gravity is 4&#x00B7;07, and the unit cell dimension is 10&#x00B7;59 &#x00C5;. After deduction of impurities the following formula was obtained (Na<sub>0&#x00B7;03</sub> K<sub>0&#x00B7;02</sub> Mg<sub>0&#x00B7;05</sub> Ca<sub>0&#x00B7;09</sub> Ba<sub>0&#x00B7;36</sub> Ln<sub>0&#x00B7;05</sub> Th<sub>0&#x00B7;01</sub> Pb<sub>0&#x00B7;004</sub>) (Ti<sub>0&#x00B7;21</sub> Nb<sub>1&#x00B7;78</sub> Ta<sub>0&#x00B7;01</sub>) (H<sub>2</sub>O)<sub>1&#x00B7;64</sub> O<sub>5&#x00B7;52</sub>.</p>
<p>Comparison of the calculated formula, essentially <italic>A</italic><sub>0&#x00B7;614</sub> <italic>B</italic><sub>2</sub> (H<sub>2</sub>O)<sub>1&#x00B7;64</sub> O<sub>5&#x00B7;52</sub> with the ideal pyrochlore formula <italic>A</italic><sub>2</sub><italic>B</italic><sub>2</sub>O<sub>6</sub>F indicates important deficiencies in the structure. Differential thermal analysis shows a large endothermic peak at 340&#x00B0; C and moderate exothermic peaks at 480 and 780&#x00B0; C. In its physical, chemical, X-ray, and thermal properties the Mrima pandaite is similar to pandaites described from other localities.</p>
<p>The nature of the alteration of primary pyrochlore to pandaite has been studied using an electron probe.</p></abstract>
</article-meta>
</front>
</article>
