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<front>
<journal-meta>
<journal-id journal-id-type="archive">gsminmag</journal-id>
<journal-title>Mineralogical Magazine</journal-title>
<abbrev-journal-title abbrev-type="full">Mineralogical Magazine</abbrev-journal-title>
<issn pub-type="ppub">0026-461X</issn>
<publisher>
<publisher-name>Mineralogical Society</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.1180/minmag.1960.032.251.05</article-id>
<title-group>
<article-title>A Thermodynamic Analysis of the System Anorthite-&#x00C5;kermanite</article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>De Wys</surname>
<given-names>E. Christiaan</given-names></name>
<degrees>M.A., Ph.D.</degrees>
<aff>International Business Machines Corporation, Kingston, New York, U.S.A.</aff></contrib></contrib-group>
<pub-date pub-type="ppub">
<month>12</month>
<year>1960</year>
</pub-date>
<volume>32</volume>
<issue>251</issue>
<fpage>644</fpage>
<lpage>649</lpage>
<copyright-statement>Copyright &#x00A9; 1960, The Mineralogical Society</copyright-statement>
<copyright-year>1960</copyright-year>
<abstract>
<title>Summary</title>
<p>From thermodynamic considerations of the system anorthite-&#x00E5;kermanite it appears that the melts in this system are ionic in nature. The liquidus relation in this system would thus seem to afford confirmation of the theory, based on conductivity measurements, that silicate melts such as molten anorthite dissociate into such ions as Ca<sup>2+</sup> and (Al<sub>2</sub>Si<sub>2</sub>O<sub>8</sub>)<sup>2&#x2212;</sup>.</p>
<p>Further thermodynamic calculations involving no unreasonable assumption lead to a close reproduction of the experimental liquidus curve of &#x00E5;kermanite. This lends added strength to the belief in the stable existence of &#x00E5;kermanite down to the eutectic; no evidence in support of the claim that &#x00E5;kermanes becomes unstable below 1 325&#x00B0; C. (Osborn and Schairer, 1941) was encountered.</p>
<p>According to Osborn <italic>et al</italic>. (1954) the presence of substantial Ca<sup>2+</sup> increases the desulphurizing potential of blast furnace slag. The thermodynamic treatment of the binary system anorthite-&#x00E5;kermanite leads to the conclusion that both phases dissociate in the molten state and in mutual solution to yield Ca<sup>2+</sup>; it therefore appears probable that a high concentration of these minerals in the slag would have a salutary effect on the slag chemistry.</p></abstract>
</article-meta>
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