<?xml version="1.0"?>
<!DOCTYPE article SYSTEM "journalpublishing.dtd">
<article article-type="research-article">
<front>
<journal-meta>
<journal-id journal-id-type="archive">gsminmag</journal-id>
<journal-title>Mineralogical Magazine</journal-title>
<abbrev-journal-title abbrev-type="full">Mineralogical Magazine</abbrev-journal-title>
<issn pub-type="ppub">0026-461X</issn>
<publisher>
<publisher-name>Mineralogical Society</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.1180/minmag.1959.032.244.03</article-id>
<title-group>
<article-title>A Hydrated Barium-Strontium Pyrochlore in a Biotite Rock from Panda Hill, Tanganyika<xref ref-type="author-notes" rid="FN1">1</xref></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>J&#x00E4;ger</surname>
<given-names>E.</given-names>
</name><degrees>Ph.D.</degrees></contrib>
<contrib contrib-type="author">
<name>
<surname>Niggli</surname>
<given-names>E.</given-names>
</name><degrees>Ph.D.</degrees></contrib>
<aff>Min.-Petr. Inst., University of Berne, Switzerland</aff></contrib-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>van der Veen</surname>
<given-names>A. H.</given-names>
</name><degrees>Geol. Drs.</degrees>
<aff>Min. Petr. Dept., Research Laboratory of the Billiton Maatschappij N.V., Hollandsche Metallurgische Bedrijven N.V., Arnhem, Netherlands.</aff></contrib></contrib-group>
<author-notes>
<fn fn-type="other" id="FN1"><label>1</label><p>Published by permission of the N.V. Billiton Maatschappij and the Colonial Development Corporation.</p></fn></author-notes>
<pub-date pub-type="ppub">
<month>3</month>
<year>1959</year>
</pub-date>
<volume>32</volume>
<issue>244</issue>
<fpage>10</fpage>
<lpage>25</lpage>
<copyright-statement>Copyright &#x00A9; 1959, The Mineralogical Society</copyright-statement>
<copyright-year>1959</copyright-year>
<abstract>
<title>Summary</title>
<p>A hydrated barium-strontium pyrochlore with only subordinate amounts of Ca and Na has been found in a weathered biotite rock (contact-rock of a carbonatite) from Panda Hill, Tanganyika, as small euhedral yellowish-grey cubic crystals (showing the combination of the octahedron and the cube) in a rock containing euhedral biotite, some orthoclase, and several other minerals. Hydrated Ba-Sr pyrochlore is isotropic, the refractive index varies from 2&#x00B7;07 to 2&#x00B7;10. The reflectivity (vertical illumination) is 13&#x00B7;2 &#x0025;. H. <inline-formula><mml:math><mml:mrow>
<mml:mn>4</mml:mn><mml:mstyle scriptlevel='+1'>
<mml:mfrac>
<mml:mn>1</mml:mn>
<mml:mn>2</mml:mn>
</mml:mfrac>
</mml:mstyle>
<mml:mo>&#x2212;</mml:mo><mml:mn>5</mml:mn>
</mml:mrow></mml:math></inline-formula>&#x2013;5 Poor &#x007B;111&#x007D; cleavage. The pyrochlore structure (space-group <inline-formula><mml:math><mml:mrow><mml:msubsup><mml:mrow><mml:mi>O</mml:mi></mml:mrow><mml:mrow><mml:mi>h</mml:mi></mml:mrow><mml:mrow><mml:mn>7</mml:mn></mml:mrow></mml:msubsup><mml:mo>&#x2212;</mml:mo><mml:mi>Fd</mml:mi><mml:mn>3</mml:mn><mml:mi>m</mml:mi></mml:mrow></mml:math></inline-formula>) and the unit-cell dimensions (<italic>a</italic> 10&#x00B7;562 &#x00C5;.) are derived from X-ray powder and Weissenberg photographs. The calculated specific gravity is 4&#x00B7;01 (observed, 4&#x00B7;00 on dried material). Chemical analysis gives BaO 12&#x00B7;5, SrO 6&#x00B7;4, Na<sub>2</sub>O 0&#x00B7;28, K<sub>2</sub>O 0&#x00B7;25, CaO 1&#x00B7;35, rare earths (mainly Ce<sub>2</sub>O<sub>3</sub>) 2, ThO<sub>2</sub> 0&#x00B7;6, FeO 0&#x00B7;45, TiO<sub>2</sub> 3&#x00B7;9, Nb<sub>2</sub>O<sub>5</sub> 67&#x00B7;0, Ta<sub>2</sub>O<sub>5</sub> 0&#x00B7;22, H<sub>2</sub>O+ 4&#x00B7;0, other constituents 2&#x00B7;21, total 101&#x00B7;16. After deduction for impurities the following formula resulted: (Ba<sub>0&#x00B7;30</sub>Sr<sub>0&#x00B7;22</sub>Ca<sub>0&#x00B7;05</sub>Ce<sub>0&#x00B7;04</sub>Na<sub>0&#x00B7;03</sub>Fe<sub>0&#x00B7;02</sub>K<sub>0&#x00B7;01</sub>Th<sub>0&#x00B7;01</sub>)(Nb<sub>1&#x00B7;83</sub>Ta<sub>0&#x00B7;004</sub>Ti<sub>0&#x00B7;17</sub>)O<sub>5&#x00B7;61</sub>(H<sub>2</sub>O)<sub>0&#x00B7;80</sub>.</p>
<p>The ideal formula for pyrochlore is <italic>A</italic><sub>2</sub><italic>B</italic><sub>2</sub><italic>O</italic><sub>6</sub>(F,OH). In the mineral described only a third of the <italic>A</italic>-positions are occupied by Ba, Sr, etc. Infra-red spectrophotometry does not indicate hydroxyl-groups. When the mineral is treated with TINO<sub>3</sub> solution the intensities of the X-ray diffraction lines 333/511, and 444 are changed; hydrated Ba-Sr pyrochlore shows a certain exchange-capacity.</p>
<p>The name <italic>pandaite</italic>, from Panda Hill, is proposed for the new mineral.</p></abstract>
</article-meta>
</front>
</article>
