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<front>
<journal-meta>
<journal-id journal-id-type="archive">gsminmag</journal-id>
<journal-title>Mineralogical Magazine</journal-title>
<abbrev-journal-title abbrev-type="full">Mineralogical Magazine</abbrev-journal-title>
<issn pub-type="ppub">0026-461X</issn>
<publisher>
<publisher-name>Mineralogical Society</publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.1180/minmag.1924.020.104.01</article-id>
<title-group>
<article-title>Some Anomalous Optical Properties of Freshly-Prepared Mixed Crystals of the Seignette Salts</article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname>Buckley</surname>
<given-names>Harold E.</given-names>
</name><degrees>M.Sc. (Vict.), F.C.S.</degrees>
<aff>Assistant Lecturer in Crystallography</aff></contrib></contrib-group>
<pub-date pub-type="ppub">
<month>3</month>
<year>1924</year>
</pub-date>
<volume>20</volume>
<issue>104</issue>
<fpage>159</fpage>
<lpage>172</lpage>
<copyright-statement>Copyright &#x00A9; 1924, The Mineralogical Society</copyright-statement>
<copyright-year>1924</copyright-year>
<abstract>
<title>Summary</title>
<p>I. It is shown that freshly-prepared rhombic crystals of the mixed Seignette salts exhibit abnormal interference-figures. The type of dispersion observed in freshly-prepared crystals is that belonging properly to the monoclinic system, viz. crossed dispersion, of the &#x2018;borax&#x2019; type. The extent of crossed dispersion varies with the composition of the mixed crystals and rises to a maximum of 75&#x00B0; for the 45 % sodium-potassium tartrate mixture.</p>
<p>II. The effect observed in freshly-prepared crystals does not persist, but gradually disappears, the process occupying from one week to three or four months.</p>
<p>III. Increase of temperature hastens the process of change. The most pronounced cases of crossed dispersion disappeared on uniform heating to 30&#x00B0; or 40&#x00B0; C. in less than a week.</p>
<p>IV. The effect is shown to be independent of the concentration around the crystal of either ammonia or water-vapour.</p>
<p>V. An interesting feature of the change to be observed on leaving these crystals to stand is that there is a change in optic axial angle for all colours in addition to a closing in to coincidence of optic axial planes. The maximum change of optic axial angle for any section observed was that of 40&#x00B0; for yellow-green light with the 60 % sodium-potassium tartrate mixture. The observations indicate that there is <italic>no uniaxiality</italic> for any colour so long as crossed dispersion persists.</p></abstract>
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